Carbon dioxide (CO₂) Lasers

April 1, 2025

Physicists in the US have demonstrated a novel technique to detect radioactive materials remotely using carbon dioxide (CO₂) lasers.

About Carbon Dioxide (CO₂) Lasers

  • The first CO₂ laser was developed by Indian-American scientist C.K.N. Patel.
  • It is a four-level molecular gas laser that operates using vibrational energy states of CO₂ molecules.
  • Highly efficient, producing high-power continuous or pulsed output.
  • Structure: A CO₂ molecule consists of one carbon atom at the center and two oxygen atoms on either side. It vibrates in three independent modes:
    • Symmetric Stretching Mode: Oxygen atoms move simultaneously towards or away from the fixed carbon atom.
    • Bending Mode: Carbon and oxygen atoms vibrate perpendicular to the molecular axis.
    • Asymmetric Stretching Mode: Oxygen atoms move in one direction, while the carbon atom moves in the opposite direction.
  • Principle of CO₂ Laser: The laser transition occurs between vibrational energy states of CO₂ molecules. Energy is transferred from excited nitrogen (N₂) molecules to CO₂, achieving the population inversion necessary for laser action.

Characteristics of CO₂ Laser

  • Type: Molecular gas, four-level laser.
  • Active medium: Gas mixture of CO₂, N₂, and He.
  • Pumping Method: Electrical discharge.
  • Optical Resonator: Concave mirrors.
  • Power Output: Up to 10 kW.
  • Nature of Output: Continuous wave (CW) or pulsed wave.
  • Wavelength: 9.6 μm & 10.6 μm (Infrared region).

How does the Detection Work?

  • Radioactive decay and ionisation: When a material undergoes radioactive decay, it emits charged particles (alpha, beta, or gamma rays) that ionize the surrounding air, creating plasma.
  • Avalanche effect: The free electrons in plasma gain energy and collide with other atoms, releasing more electrons. This self-sustaining process is called avalanche breakdown and leads to a chain reaction of ionization.
  • Laser characteristics: Researchers used a carbon-dioxide (CO₂) laser emitting long-wave infrared (LWIR) radiation at 9.2 micrometres. The longer wavelength reduces unwanted ionization and improves sensitivity.
  • Detection mechanism: The laser accelerates seed electrons in the plasma, creating microplasma balls. These microplasmas generate a measurable optical backscatter that can be detected and analyzed.
  • Fluorescence imaging: Used to analyze the plasma formation dynamics and understand the distribution of seed electrons.
  • Mathematical model: Developed to predict backscatter signals based on plasma seed densities.
    • Validation: The model accurately reproduced experimental results, confirming the reliability of the detection technique.

Advancements in Detection Range

Parameter

Previous Techniques

CO₂ Laser Technique

Alpha particle detection

1 meter

10 meters (10x improvement)

Gamma ray detection (Cs-137)

Limited capability

Up to 100 meters

Potential future range

~10 meters max

Possibly 1 km+ with improvements

  • Alpha particles: Successfully detected from 10 meters away (10x improvement over previous methods).
  • Gamma rays (Cs-137): Could potentially be detected from 100 meters away by scaling up laser optics.

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