Lithium

May 24, 2025

A recent study published in Science Advances by Duke University has uncovered distinctive geochemical properties of lithium-rich brines found in salt pans (salars) in South America and Asia.

About Lithium

  • Lithium is a lightweight, silvery-white alkali metal with the lowest density among metals.
  • It reacts vigorously with water and makes alloys with aluminium and magnesium, enhancing material strength and reducing weight—ideal for aerospace and battery technologies.
  • Lithium, also known as “white gold”, is a critical mineral essential for the renewable energy sector, especially in the production of electric vehicle (EV) batteries and energy storage systems.
  • Around 40% of global lithium supply is derived from evaporative brine mining in salt flats (salars) of the central Andes (Chile, Argentina, Bolivia—“Lithium Triangle”) and the Tibetan Plateau.

Key Findings

  • The study focused on Salar de Uyuni in Bolivia, the world’s largest lithium brine reserve, located in a high-altitude arid region.
  • It was found that, unlike seawater, where carbonate molecules dominate pH regulation, the pH of these brines is controlled almost entirely by boron compounds.
  • Boron, present in the form of boric acid and borates, was found to determine the pH and alkalinity of natural brines.
  • During brine evaporation in mining ponds:
    • The concentration of boron increases.
    • Boric acid breaks down, releasing hydrogen ions, which lowers the pH and makes the brine highly acidic.

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